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A comparative thermogravimetric study of waterlogged archaeological and sound woods

机译:浸水考古木和声木的比较热重研究

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Waterlogged archaeological woods Pinus pinaster and Fagus sylvatica L. were analyzed by using TG technique. Degradation processes ascribable to the holocellulose decay were evidenced at nearly the same temperature for sound and archaeological samples. The residual matters at 600 and 900 °C of the sound woods are much lower than those of archaeological waterlogged woods in agreement with the presence of inorganic materials encapsulated during the burial into the marine environment. It was proposed a new protocol to rapidly calculate the maximum water content parameter, which is related to the wood degradation state. TG experiments at variable heating rates were performed to obtain kinetic parameters for the degradation process. The Flynn–Wall–Ozawa and Friedman approaches allowed us to calculate the activation energy, which is significantly different for the sound and the archaeological woods.
机译:利用TG技术分析了淹水的考古木材的松林和水青冈。对于声音和考古样品,在几乎相同的温度下证明了由于全纤维素降解而引起的降解过程。与埋葬到海洋环境中的无机材料的存在相一致,在600和900°C时,稳固木材的残留物比考古浸水木材的残留物低得多。提出了一种新的协议来快速计算最大含水量参数,该参数与木材的降解状态有关。进行了可变升温速率的TG实验,以获取降解过程的动力学参数。 Flynn-Wall-Ozawa和Friedman方法使我们能够计算活化能,这对于声音和考古树林而言是显着不同的。

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