Triblock copolymer anion exchange membranes bearing alkyl-tethered cycloaliphatic quaternary ammonium-head-groups for fuel cells

摘要

To explore highly conductive and alkaline stable anion exchange membrane (AEM) materials, triblock copolymers bearing alkyl-tethered cycloaliphatic quaternary ammonium-head-groups are prepared via nucleophilic substitution, Friedel-Crafts acylation, ketone reduction and Menshutkin reaction. The designed triblock copolymers composed of quaternized poly(phenylene oxide) segments and poly(ether sulfone) segments are responsible for the microphase separated morphology and well-connected ion domains, as confirmed by transmission electron microscopy. The highest conductivity, up to 105.1 mS cm(-1) at 80 degrees C is achieved for the AEM with ionic exchange capacity (IEC) of 1.81 meq g(-1) Furthermore, the AEMs show robust alkaline stability due to the alkyl-tethered cation-head-groups structure. High retention of hydroxide conductivity (88.9%) and IEC (91.2%) is observed for the AEMs via degradation test in a 1 M aqueous KOH solution at 80 degrees C for 480 h. Based on the AEM with high conductivity, a H-2/O-2 fuel cell achieves a peak power density of 176.5 mW cm(-2) (80 degrees C) at a current density of 500 mA cm(-2). (C) 2017 Elsevier B.V. All rights reserved.