Extremely fine structured cathode for solid oxide fuel cells using Sr-doped LaMnO3 and Y2O3-stabilized ZrO2 nano-composite powder synthesized by spray pyrolysis

摘要

A solid oxide fuel cell (SOFC) for high power density operation was developed with a microstructure controlled cathode using a nano-composite powder of Sr-doped LaMnO3 (LSM) and Y2O3-stabilized ZrO2 (YSZ) synthesized by spray pyrolysis. The individual LSM-YSZ nano-composite particles, formed by crystalline and amorphous nano-size LSM and YSZ particles, showed spherical morphology with uniform particle size. The use of this powder for cathode material led to an extremely fine microstructure, in which all the LSM and YSZ grains (approximately 100-200 nm) were highly dispersed and formed their own network structures. This microstructure was due to the two phase electrode structure control using the powder, namely, nano-order level in each particle and micro-order level between particles. An anode-supported SOFC with the LSM-YSZ cathode using humidified H-2 as fuel and ambient air as oxidant exhibited high power densities, such as 1.29 W cm(-2) under a voltage of 0.75 V and a maximum power density of 2.65 W cm(-2) at 800 degrees C. Also, the SOFC could be stably operated for 250 h with no degradation, even at a high temperature of 800 degrees C. (C) 2016 Elsevier B.V. All rights reserved.