Organocatalysis of Asymmetric Epoxidation Mediated by Iminium Salts under Nonaqueous Conditions

Philip C. Bulman Page; David Barros; Benjamin R. Buckley; Adel Ardakani; Brian A. Marples

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Organocatalysis of Asymmetric Epoxidation Mediated by Iminium Salts under Nonaqueous Conditions

机译：非水条件下亚硝酸盐介导的不对称环氧化的有机催化

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摘要

The first nonaqueous conditions are described for catalytic asymmetric epoxidation mediated by iminium salt organocatalysts, providing ee values of up to 67%.

机译：描述了由亚胺盐有机催化剂介导的催化不对称环氧化的第一个非水条件，其ee值高达67％。

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来源
《The Journal of Organic Chemistry》 |2004年第10期|p.3595-3597|共3页
作者
Philip C. Bulman Page; David Barros; Benjamin R. Buckley; Adel Ardakani; Brian A. Marples;
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作者单位

Department of Chemistry, Loughborough University, Loughborough, Leicestershire LE11 3TU, England;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类有机化学;
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入库时间 2022-08-18 00:03:25

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1. Organocatalysis of asymmetric epoxidation mediated by iminium salts: comments on the mechanism [J] . Page PCB, Barros D, Buckley BR, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2005,第21期

机译：亚胺盐介导的不对称环氧化的有机催化：机理的评论
2. Asymmetric organocatalysis of epoxidation by iminium salts under non-aqueous conditions [J] . Philip C. Bulman Page, Benjamin R. Buckley, David Barros, Tetrahedron . 2007,第25期

机译：亚胺盐在非水条件下环氧化的不对称有机催化
3. Organocatalysis of asymmetric epoxidation by iminium salts using sodium hypochlorite as the stoichiometric oxidant [J] . Page PCB, Parker P, Buckley BR, Tetrahedron . 2009,第15期

机译：次氯酸钠作为化学计量氧化剂的亚胺盐对有机化合物的不对称环氧化反应的有机催化
4. Photosensitization with benzochlorin iminium salts [C] . David Kessel, Wayne State Univ. School of Medicine, Detroit, Optical Methods for Tumor Treatment and Detection: Mechanisms and Techniques in Photodynamic Therapy III . 1994

机译：苯并二氯亚胺亚胺盐光敏化
5. Synthesis of chiral vinylsulfonium salts and their application in the synthesis of the mitomycin skeleton (Asymmetric epoxidation). [D] . Kim, Kyung Hee. 2001

机译：手性乙烯基s盐的合成及其在丝裂霉素骨架合成中的应用（不对称环氧化）。
6. The Emerging Utility of αβ-Unsaturated Acylammonium Salts for Asymmetric Organocatalysis [O] . Dr. Sreekumar Vellalath, Prof. Dr. Daniel Romo -1

机译：αβ-不饱和酰基铵盐在不对称有机催化中的新兴效用
7. Asymmetric Organocatalysis of Epoxidation by Iminium Salts under Non-Aqueous Conditions [O] . Benjamin R. Buckley, David Barros, A John Blacker, 2015

机译：非水条件下I盐对环氧化的不对称有机催化作用

Organocatalysis of Asymmetric Epoxidation Mediated by Iminium Salts under Nonaqueous Conditions

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