Synthesized silicon-substituted hydroxyapatite coating on titanium substrate by electrochemical deposition

摘要

Silicon-substituted hydroxyapaptite (Si-HA) coatings were prepared on titanium substrates by electrolytic deposition technique in electrolytes containing Ca~(2+), PO_4~(3-) and SiO_3~(2-) ions with various SiO_3~(2-)/(PO_4~(3-)+ SiC>_3~(2-)) molar ratios(n_(si)). The deposition was all conducted at a constant voltage of 3.0 V, with titanium substrate as cathode and platinum as anode, for 1 h at 85°C. The coatings thus prepared were characterized with inductively coupled plasma (ICP), X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), field-emission-type scanning electron microscope (FSEM). The results show that the silicon amount in the coatings increases linearly to about 0.48 wt% at first with increasing n_(si) between 0 and 0.03, then increases slowly to about 0.55 wt% between 0.03 and 0.10 and finally maintains almost at a level around 0.55 wt% between 0.10 and 0.30. The tree-like Si-HA crystals are observed in the coatings prepared in the electrolyte of n_(si) = 0.20. And the presence of silicon in electrolytes decreases the thickness of the coatings, with effect being more significant as n_(si) increased. Additionally, the substitution of Si causes some OH~- loss and changes the lattice parameters of hydroxyapatite (HA).