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Synthesis and magnetic properties of (Fe, Sn) co-doped In_2O_3 nanoparticles

机译:(Fe,Sn)共掺杂In_2O_3纳米粒子的合成与磁性

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摘要

The iron (Fe) and tin (Sn) co-doped indium oxide (In_2O_3) nanoparticles at different Fe doping concentrations were prepared by solid state reaction and studied for their structural, optical and magnetic properties. The XRD patterns confirmed the cubic structure of all the undoped and co-doped samples. The average crystallite size decreased on increasing from 41 to 32 nm by increase of Fe doping concentration from 5 to 15 at.%. The optical band gap of the samples was found to decrease from 2.89 to 2.77 eV by increasing the Fe dopant concentration. The magnetic properties of the nanoparticles were studied using vibrating sample magnetometer at room temperature and at 100 K by applying the field ±75,000 Oe perpendicular to the sample. The magnetization increased with increase of applied magnetic field and no saturation was observed in all the samples. The similar behavior was observed for the nanoparticles studied at 100 K.
机译:通过固相反应制备了不同Fe掺杂浓度的铁(Fe)和锡(Sn)共掺杂的氧化铟(In_2O_3)纳米粒子,并对其结构,光学和磁性进行了研究。 XRD图谱证实了所有未掺杂和共掺杂样品的立方结构。通过将Fe掺杂浓度从5原子%增加到15原子%,平均晶粒尺寸从41纳米增加到32纳米。发现通过增加Fe掺杂剂浓度,样品的光学带隙从2.89降低到2.77eV。使用振动样品磁力计在室温和100 K下通过垂直于样品施加±75,000 Oe的磁场来研究纳米颗粒的磁性。磁化强度随施加磁场的增加而增加,并且在所有样品中均未观察到饱和。对于在100 K下研究的纳米颗粒,观察到了相似的行为。

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  • 来源
    《Journal of materials science 》 |2017年第24期| 18977-18985| 共9页
  • 作者单位

    Thin Film Laboratory, Centre for Crystal Growth, VIT University, Vellore, Tamilnadu 632014, India;

    Thin Film Laboratory, Centre for Crystal Growth, VIT University, Vellore, Tamilnadu 632014, India;

    Department of Physics, VIT-AP University, Amaravati, Andhra Pradesh 522237, India;

    Materials Physics Division, Indira Gandhi centre for Atomic Research, Kalpakkam, Tamilnadu 603102, India;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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