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Smoke suppression properties of ferrite yellow on flame retardant thermoplastic polyurethane based on ammonium polyphosphate

机译:铁氧体黄在基于聚磷酸铵的阻燃热塑性聚氨酯上的抑烟性能

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摘要

This article mainly studies smoke suppression properties and synergistic flame retardant effect of fer-rite yellow (FeOOH) on flame retardant thermoplastic polyurethane (TPU) composites using ammonium polyphosphate (APP) as a flame retardant agent. Smoke suppression properties and synergistic flame retardant effect of FeOOH on flame retardant TPU composites were intensively investigated by smoke density test (SDT), cone calorimeter test (CCT), scanning electron microscopy (SEM), and thermal-gravimetric analysis (TGA). Remarkably, the SDT results show that FeOOH can effectively decrease the amount of smoke production with or without flame. On the other hand, the CCT data reveal that the addition of FeOOH can apparently reduce heat release rate (HRR), total heat release (THR), and total smoke release (TSR), etc. Here, FeOOH is considered to be an effective smoke suppression agent and a good synergism with APP in flame retardant TPU composites, which can greatly improve the structure of char residue realized by TGA and SEM results.
机译:本文主要研究铁氧体黄(FeOOH)对以聚磷酸铵(APP)为阻燃剂的阻燃热塑性聚氨酯(TPU)复合材料的抑烟性能和协同阻燃效果。通过烟雾密度测试(SDT),锥形量热仪测试(CCT),扫描电子显微镜(SEM)和热重分析(TGA),深入研究了FeOOH对阻燃TPU复合材料的抑烟性能和协同阻燃效果。值得注意的是,SDT结果表明,FeOOH可以有效地减少有或没有火焰的烟雾产生量。另一方面,CCT数据表明添加FeOOH可以明显降低放热率(HRR),总放热(THR)和总烟气释放(TSR)等。在这里,FeOOH被认为是有效的。阻燃剂TPU复合材料中的抑烟剂和与APP的良好协同作用,可大大改善TGA和SEM结果实现的残炭结构。

著录项

  • 来源
    《Journal of Hazardous Materials》 |2014年第15期|114-121|共8页
  • 作者单位

    College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao, 266042, PR China;

    College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao, 266042, PR China;

    College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao, 266042, PR China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Smoke suppression; FeOOH; Thermoplastic polyurethane; Ammonium polyphosphate;

    机译:抑制烟雾;FeOOH;热塑性聚氨酯;聚磷酸铵;

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