Smoke suppression properties of fumed silica on flame-retardant thermoplastic polyurethane based on ammonium polyphosphate

摘要

In this paper, fumed silica has been used as smoke suppression and flame-retardant synergism in thermoplastic polyurethane (TPU) composites based on ammonium polyphosphate (APP). And, the synergistic smoke suppression property and flame-retardant effect of fumed silica in flame-retardant TPU composites are mainly intensively investigated by several methods, including smoke density test (SDT), cone calorimeter test (CCT), scanning electron microscopy (SEM), limiting oxygen index, and thermogravimetric analysis. The results of SDT show that fumed silica can significantly decrease smoke production of flame-retardant TPU composites. The results of CCT present that the addition of fumed silica can effectively reduce smoke production rate, total smoke release, smoke factor, heat release rate, and mass loss in the combustion process of flame-retardant TPU composites. The SEM results show that fumed silica can improve the quality of char residue after cone calorimeter test. All the results show that fumed silica is an effective smoke suppression agent and a good flame-retardant synergism with APP in TPU composites.