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Decomposition of EDTA in aqueous solution by UV / H_2o_2 PROCESS

机译:UV / H_2o_2工艺降解水溶液中的EDTA。

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摘要

The decomposition of EDTA in aqueous solution by UV/H_2O_2 process was studied under various solution pH values, H_2O_2 dosages, UV light intensities, temperatures and concentrations of Cu~2+ in order to determine the completeness of decomposition. The removal and mineraliza- tion rates of EDTA by UV/H_2O_2 process increased with increasing light intensity possibly due to the increased generation rate of hydroxyl free radicals. Free copper ions might serve as catalysts to accelerate the reaction rate, except in alkaline conditions, where copper ion would precipitate ad hydroxide.
机译:研究了在溶液pH值,H_2O_2剂量,紫外线强度,温度和Cu〜2 +浓度等条件下,UV / H_2O_2过程中EDTA在水溶液中的分解过程,确定了分解的完全性。 UV / H_2O_2工艺对EDTA的去除和矿化速率随光强度的增加而增加,这可能是由于羟基自由基的生成速率增加所致。游离的铜离子可能充当催化剂以加快反应速度,但在碱性条件下除外,在碱性条件下铜离子会沉淀出氢氧化物。

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