Experimental and theoretical study on thermal kinetics and reactive mechanism of nitrocellulose pyrolysis by traditional multi kinetics and modeling reconstruction

摘要

Nitrocellulose (NC) has been applied in many fields of daily life and military industry, but its instability brings large danger during storage and usage, which greatly limits its application. In this study, decomposition behavior and reaction model of NC were explored. To obtain its kinetic triplets during decomposition, NC samples were heated in nitrogen atmosphere with different heating rates of 5, 10, 15, 20 degrees C min(-1), respectively. A 3-th order reaction model was obtained by model fitting methods. Meanwhile, the relationship between activation energy and conversion was obtained by multi isoconversional methods, including KAS, FR, FWO, and Advanced Vyazovkin methods. Then the reaction model was reconstructed by introducing adjustment functions with result of an expression of f(alpha) = 19.38193 alpha(1.41177)(1-alpha)(4.60503).