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Solar Light Induced Degradation of Reactive Dye Using Photocatalysis

机译:太阳光诱导的光催化降解活性染料

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Outdoors experiment with natural solar light instead of using artificial UV light was also conducted to investigate alternative energy source applicability on organics degradation. The results of this study were as follows. Degradation of the reactive dye, Red 120, with TiO_2/solar light was enhanced by augmentation in TiO_2 loading, and UV light intensity but was inhibited by increase in initial dye concentration. With both solar light illumination and TiO_2 present, reactive dye was more effectively eliminated than with either solar light or TiO_2 alone. Photocatalytic removal efficiency of reactive dye increased with increasing TiO_2 dosage. However, over 1.5gL~(-1) of TiO_2 dosage, the efficiency reached a plateau. The degradation rate of reactive dye, Red 120, was strongly dependent on initial dye concentration, and all the experimental data were fit to the first-order rate equation. Photocatalytic degradation of reactive dye increased linearly with increasing UV light intensity. It is found that the presence of thick clouds in the sky markedly increased the time required for degradation of reactive dye. On the basis of these experimental observations, the photo-oxidation degradation of reactive dye using TiO_2 under solar light irradiation can be feasible application of the advanced oxidation process.
机译:还进行了户外自然光代替人造紫外线的实验,以研究替代能源对有机物降解的适用性。这项研究的结果如下。 TiO_2 /太阳光的增加可增强活性染料Red 120对TiO_2 /太阳光的降解,但受初始染料浓度增加的抑制。既有太阳光照射又有TiO_2存在,与单独使用太阳光或TiO_2相比,活性染料的清除效果更好。活性染料的光催化去除效率随着TiO_2用量的增加而增加。但是,当TiO_2用量超过1.5gL〜(-1)时,效率达到了平稳。活性染料Red 120的降解速率在很大程度上取决于初始染料浓度,所有实验数据均符合一级速率方程。活性染料的光催化降解随着紫外线强度的增加而线性增加。发现天空中厚厚的云的存在显着增加了降解活性染料所需的时间。基于这些实验观察,在太阳光照射下使用TiO_2的活性染料的光氧化降解可能是先进氧化工艺的可行应用。

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