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Ultrasound Assisted Hybrid Carbon Epoxy Composites Containing Carbon Nanotubes

机译:含碳纳米管的超声辅助杂化碳环氧复合材料

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A simple approach has been reported toward the development of hybrid nanolmicrofiber composite structures with improved mechanical properties. Ultrasound assisted atomiza-tion process has been utilized for depositing carbon nanotubes (CNTs) on the surface of carbon fiber (CF) cloth using dilute solutions of CNTs in N, N-dimethylformamide (DMF). Dilute solutions with three different CNT concentrations such as 1 × 10~(-4) glml, 5 × 10~(-4) glml, and 10 × 10~(-4) glml were fed into an ultrasonic atomizer probe using a positive displacement syringe pump and sprayed directly on CF cloth rested on a hot plate inside a deposition chamber. Several layers of hybrid CF cloths containing CNTs were used to fabricate composite laminates using a vacuum assisted resin transfer molding (VARTM). Although the dispersion of CNTs in DMF was found very well for all three concentrations, the distribution of CNTs on CFs was only found homogeneous for 1 × 10~(-4) glml solution. It was found that the hybrid composite containing 0.3 wt. % CNTs loading fabricated using 1× 10~(-4) glml solution showed about 25% improvement in flexural strength, although moderate improvement in flexure modulus was achieved for all three concentrations. The improved strength is believed to be due to homogeneous distribution of CNTs, which resulted in increased surface roughness and mechanical interlocking between fibers and matrix.
机译:已经报道了一种简单的方法来开发具有改善的机械性能的杂化纳米微纤维复合结构。超声辅助雾化工艺已被用于使用碳纳米管在N,N-二甲基甲酰胺(DMF)中的稀溶液在碳纤维(CF)布表面沉积碳纳米管(CNT)。将具有三种不同CNT浓度(例如1×10〜(-4)glml,5×10〜(-4)glml和10×10〜(-4)glml)的稀释溶液通过正位移注入超声雾化器探头中注射泵直接喷在放置在沉积室内热板上的CF布上。使用真空辅助树脂传递模塑(VARTM),将多层包含CNT的混合CF布用于制造复合材料层压板。尽管在所有三个浓度下都发现CNTs在DMF中的分散性很好,但是仅在1×10〜(-4)glml溶液中发现CNTs在CFs上的分布是均匀的。发现含有0.3重量%的杂化复合材料。尽管在所有三个浓度下均获得了适度的挠曲模量改善,但使用1×10〜(-4)glml溶液制备的CNTs负载量显示出约25%的挠曲强度改善。据信强度的提高归因于CNT的均匀分布,这导致表面粗糙度增加以及纤维与基质之间的机械互锁。

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