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A Review of Temperature Influence on Adsorption Mechanism and Conformation of Water Soluble Polymers on the Solid Surface

机译:温度对固体表面水溶性聚合物吸附机理和形态的影响研究进展

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摘要

The temperature effect on adsorption behavior of water soluble polymer and structure of its adsorption layer formed on the solid surface is presented. The main reasons for such problem explanation are wide application possibilities of stabilization-flocculation properties of polymers in many technological and ecological processes and very poor knowledge about temperature dependences of high-molecular compounds adsorption on the solid surface. To systematize the information about the effect of temperature on polymer chain conformation on the adsorbent surface the following aspects were considered: thermodynamic and physicochemical characteristics of polymer solutions, stabilization-flocculation properties of polymers in the dispersed systems, and presentation of respective experimental results. The theoretical and experimental evidence of the temperature effect on polymer macromolecule conformation on the solid surface presented in the article can contribute to better knowledge and understanding of the adsorption process at the metal oxide-polymer solution interface in the temperature function.View full textDownload full textKeywordsFlocculation, metal oxide surface, polymer conformation, steric stabilization, temperature effectRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/01932691.2010.528332
机译:提出了温度对水溶性聚合物吸附行为的影响及其在固体表面形成的吸附层的结构。解释此类问题的主要原因是,聚合物在许多技术和生态过程中具有稳定化-絮凝性质的广泛应用可能性,以及对高分子化合物在固体表面吸附的温度依赖性的了解甚少。为了系统化有关温度对吸附剂表面上聚合物链构象的影响的信息,考虑了以下几个方面:聚合物溶液的热力学和理化特性,分散体系中聚合物的稳定絮凝特性以及各自的实验结果。本文介绍的温度对固体表面聚合物高分子构象的温度影响的理论和实验证据可有助于更好地了解和理解温度函数中金属氧化物-聚合物溶液界面处的吸附过程。查看全文下载全文关键字絮凝,金属氧化物表面,聚合物构象,位阻稳定,温度效应“,pubid:” ra-4dff56cd6bb1830b“};添加到候选列表链接永久链接http://dx.doi.org/10.1080/01932691.2010.528332

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