Spontaneous growth of diamond from MnNi solvent-catalyst using opposed anvil-type high-pressure apparatus

摘要

In this paper an overview of the application of opposed anvil-type high-pressure and high-temperature apparatus for spontaneous growth of diamond crystals by solvent-catalyst technique is presented. The process makes use of a molten Mn_(47)Ni_(53) catalyst to initiate the graphite-diamond transformation reaction. The pressure and temperature requirements to obtain reproducible spontaneous diamond crystallization were around 52.5-54 kbar and 1270-1320 ℃. The crystals had well-shaped cubo-structured morphology with the {100} and {111} faces and grain sizes of 0.2-0.5 mm. This work can stimulate future experimental exploration of spontaneous diamond crystallization by using other solvent-catalyst metals.