Trapping of ion‐implanted deuterium by lattice defects in nickel has been studied by ion‐beam‐analysis techniques in the temperature range between 30 and 380 K. The deuterium‐depth profiles were determined by measuring either the α particles or the protons from the 3He‐excited nuclear reaction D(3He,α)p, and the deuterium lattice location was obtained by means of ion channeling. Linear‐ramp annealing (1 K/min) following a 10‐keV D+ implantation in nickel produced two annealing stages at 275 and 320 K, respectively. The release‐vs‐temperature data were analyzed by solving the diffusion equation with appropriate trapping terms, yielding 0.24 and 0.43 eV for the trap‐binding enthalpies associated with the two stages, referred to as an untrapped solution site. The 0.24‐eV trap corresponds to deuterium close to the octahedral interstitial site where it is believed to be trapped at a vacancy, whereas it is suggested that the defect correlated with the 0.43‐eV trap is a multiple‐vacancy defect. The previously air‐exposed and electropolished nickel surface was essentially permeable; the surface‐recombination coefficient was determined to be K≳10-19 cm4/s at 350 K.
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机译:在30至380 K的温度范围内,已经通过离子束分析技术研究了镍中晶格缺陷对离子注入氘的俘获。通过测量α粒子或3He质子来确定氘深度分布激发的核反应D(3He,α)p和氘晶格位置是通过离子通道获得的。在镍中以10keV D +注入后进行线性斜坡退火(1 K / min),分别在275 K和320 K产生了两个退火阶段。通过使用适当的俘获项求解扩散方程来分析释放与温度数据,得出与这两个阶段相关的俘获结合焓的0.24和0.43 eV,这称为未俘获的溶液位点。 0.24 eV陷阱对应于八面体间隙位置附近的氘,据信氘在八面体间隙处被捕获,而建议与0.43 ev陷阱相关的缺陷是多空位缺陷。先前空气暴露和电抛光的镍表面基本上是可渗透的;在350 K时,表面复合系数确定为K≳10-19cm4 / s。
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