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首页> 外文期刊>Journal of Applied Physics >Role of oxygen vacancies on ferromagnetism in Fe-doped TiO_2 thin films
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Role of oxygen vacancies on ferromagnetism in Fe-doped TiO_2 thin films

机译:氧空位对掺铁TiO_2薄膜中铁磁性的作用

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Fe-doped TiO_2 rutile thin films were fabricated by reactive magnetron sputtering on SiO_2 substrates under different growth conditions, and the structure and magnetism have been systematically investigated. X-ray diffraction data, atomic force microscopy, and magnetic force microscopy confirm the absence of metallic Fe clusters or any other impurity phase. The divalent Fe ion was identified by x-ray photoelectron spectra. Room-temperature ferromagnetism has been observed for all the Fe_xTi_(1-x)O_2 (x=3%-15%) rutile films. However, the saturation magnetization (M_s) varied drastically for different pressures, doping concentrations, and annealing processes. The results show that ferromagnetism originates from the doped matrix rather than any type of magnetic cluster and the ferromagnetism is strongly correlated with the oxygen vacancies in TiO_2.
机译:在不同的生长条件下,通过反应磁控溅射在SiO_2衬底上制备了Fe掺杂的TiO_2金红石型薄膜,并对其结构和磁性进行了系统的研究。 X射线衍射数据,原子力显微镜和磁力显微镜证实没有金属铁簇或任何其他杂质相。通过X射线光电子能谱鉴定二价Fe离子。已对所有Fe_xTi_(1-x)O_2(x = 3%-15%)金红石薄膜观察到室温铁磁性。但是,饱和磁化强度(M_s)对于不同的压力,掺杂浓度和退火工艺会急剧变化。结果表明,铁磁性源于掺杂基体,而不是任何类型的磁性团簇,并且铁磁性与TiO_2中的氧空位密切相关。

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