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Detailed Analysis Of The Microwave-detected Photoconductance Decay In Crystalline Silicon

机译:微波检测结晶硅中光电导衰减的详细分析

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摘要

An approach to evaluate the microwave-detected photoconductance decay (MWPCD) is developed, which allows to extract the minority carrier lifetime as a function of the excess carrier density from a single MWPCD measurement. The method is shown to be applicable to thin (w ≤ 200 μm) silicon wafers with low minority carrier recombination at the surfaces and bulk lifetimes in the range of about 1-100 μs. Comparison of the MWPCD results with minority carrier lifetime measurements using the quasi-steady-state photoconductance method reveals very good agreement between both types of measurement. Only when the photoconductance exceeds 30% of the dark conductivity, is a deviation observed, because then the MWPCD signal is no longer directly proportional to the excess carrier density. Minority carrier trapping is found to affect the MWPCD signal only in the tail of the measured photoconductance decay. The evaluation method is used to map the interstitial iron content with high spatial resolution, as well as to determine the minority carrier trap density. An excellent agreement between numerical simulation and measured MWPCD signal is found revealing the assumptions made for the evaluation approach to be valid. This evaluation of the MWPCD measurement is well suited to characterize silicon of low purity and low crystalline quality, which is often employed to solar cells with high spatial resolution.
机译:开发了一种评估微波检测到的光电导衰减(MWPCD)的方法,该方法允许从单个MWPCD测量中提取少数载流子寿命,将其作为过量载流子密度的函数。结果表明该方法适用于表面上少数载流子复合低且堆积寿命在约1-100μs范围内的薄(w≤200μm)硅晶片。将MWPCD结果与使用准稳态光电导方法进行的少数载流子寿命测量结果进行比较,发现两种测量方法之间具有很好的一致性。仅当光电导超过暗导率的30%时,才观察到偏差,因为MWPCD信号不再与多余的载流子密度成正比。发现少数载流子捕获仅在测得的光电导衰减的尾部影响MWPCD信号。该评估方法用于绘制具有高空间分辨率的间隙铁含量,并确定少数载流子陷阱密度。发现数值模拟与测得的MWPCD信号之间有很好的一致性,这揭示了使评估方法有效的假设。对MWPCD测量的评估非常适合表征低纯度和低结晶质量的硅,硅通常用于具有高空间分辨率的太阳能电池。

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