Strain-relaxed structure in (001)/(100)-oriented epitaxial Pb(Zr,Ti)O_3 films grown on (100) SrTiO_3 substrates by metal organic chemical vapor deposition

Hiroshi Nakaki; Yong Kwan Kim; Shintaro Yokoyama; Rikyu Ikariyama; Hiroshi Funakubo; Ken Nishida; Keisuke Saito; Hitoshi Morioka; Osami Sakata; Hee Han; Sunggi Baik

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Strain-relaxed structure in (001)/(100)-oriented epitaxial Pb(Zr,Ti)O_3 films grown on (100) SrTiO_3 substrates by metal organic chemical vapor deposition

机译：通过金属有机化学气相沉积在（100）SrTiO_3衬底上生长的（001）/（100）取向外延Pb（Zr，Ti）O_3薄膜中的应变松弛结构

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Epitaxial (100)/(001)-oriented tetragonal Pb(Zr,Ti)O_3 films above 1 μm thick were grown on (100)SrTO_3 substrates by pulsed metal organic chemical vapor deposition, and the films with Zr/(Zr+Ti) ratios up to 0.43 were found to have a strain-relaxed domain structure. The domain structure determined by the volume fraction of (001) orientation (mainly decided by the thermal strain above the Curie temperature) and the lattice parameters dependent on the Zr/(Zr+Ti) ratio are explained by a geometrical model consistent with previous results for PbTiO_3 films [J. Appl. Phys. 104, 064121 (2008)].

机译：通过脉冲金属有机化学气相沉积法在（100）SrTO_3衬底上生长了厚度大于1μm的外延（100）/（001）取向的四方Pb（Zr，Ti）O_3薄膜，并形成了Zr /（Zr + Ti）薄膜。比率高达0.43被发现具有应变松弛域结构。由几何模型解释了由（001）取向的体积分数（主要由居里温度以上的热应变决定）和取决于Zr /（Zr + Ti）比的晶格参数确定的畴结构用于PbTiO_3薄膜[J.应用物理104，064121（2008）]。

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来源
《Journal of Applied Physics》 |2009年第1期|808-812|共5页
作者
Hiroshi Nakaki; Yong Kwan Kim; Shintaro Yokoyama; Rikyu Ikariyama; Hiroshi Funakubo; Ken Nishida; Keisuke Saito; Hitoshi Morioka; Osami Sakata; Hee Han; Sunggi Baik;
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作者单位

Department of Innovative Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8503, Japan;

Department of Innovative Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8503, Japan;

Department of Innovative Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8503, Japan;

Department of Innovative Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8503, Japan;

Department of Innovative Engineered Materials, Tokyo Institute of Technology, Yokohama 226-8503, Japan;

Department of Electrical Engineering, National Defense Academy, Yokohama 239, Japan;

Application Laboratory, Bruker AXS, 3-9-A, Moriya-cho, Kanagawa-ku, Yokohama 221-0022, Japan;

Application Laboratory, Bruker AXS, 3-9-A, Moriya-cho, Kanagawa-ku, Yokohama 221-0022, Japan;

Japan Synchrotron Radiation Research Institute (JASRI)/SPring-8, Kouto, Sayo-cho Sayo-gun, Hyogo 679-5198, Japan;

Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea;

Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
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1. Strain-relaxed structure in (001)/(100)-oriented epitaxial PbTiO_3 films grown on (100) SrTiO_3 substrates by metal organic chemical vapor deposition [J] . Hiroshi Nakaki, Yong Kwan Kim, Shintaro Yokoyama, Applied Physics Letters . 2007,第11期

机译：金属有机化学气相沉积在（100）SrTiO_3衬底上生长的（001）/（100）取向外延PbTiO_3薄膜中的应变松弛结构
2. Crystal structure and microstructure of epitaxial Pb(Zr,Ti)O_3 films consisting of mixed phases with tetragonal and rhombohedral symmetries grown on (100)_cSrRuO_3//(100)SrTiO_3 substrate by metalorganic chemical vapor deposition [J] . Shintaro Yokoyama, Hitoshi Morioka, Yong Kwan Kim, Journal of Materials Research . 2007,第6期

机译：金属有机化学气相沉积在（100）_cSrRuO_3 //（100）SrTiO_3衬底上生长的具有四方和菱形对称混合相的外延Pb（Zr，Ti）O_3薄膜的晶体结构和微观结构
3. Crystal structure, electrical properties, and mechanical response of (100)-/(001)-oriented epitaxial Pb(Mg_(1/3)Nb_(2/3))O_3-PbTiO_3 films grown on (100)_cSrRuO_3‖(100)SrTiO_3 substrates by metal-organic chemical vapor deposition [J] . Shintaro Yokoyama, Satoshi Okamoto, Hiroshi Funakubo, Journal of Applied Physics . 2006,第5期

机译：（100）_cSrRuO_3‖（100）上生长的（100）-/（001）取向外延Pb（Mg_（1/3）Nb_（2/3））O_3-PbTiO_3薄膜的晶体结构，电学性质和机械响应金属有机化学气相沉积法制备SrTiO_3衬底
4. X-ray Analysis of Strain Relaxed Domain Structure in (100)/(001)-oriented epitaxial PbTiO_3 thick films grown on (100)SrTiO_3 substrates [C] . Hiroshi Nakaki, Yong Kwan Kim, Shintaro Yokoyama, MRS fall meeting . 2008

机译：在（100）SrTiO_3衬底上生长的（100）/（001）取向外延PbTiO_3厚膜中的应变松弛畴结构的X射线分析
5. Strontium titanium oxide and barium(1-x) strontium(x) titanium oxide epitaxial thin films grown by plasma-enhanced metalorganic chemical vapor deposition. [D] . Liang, Shaohua. 1995

机译：通过等离子体增强的金属有机化学气相沉积法制得的锶钛氧化物和钡（1-x）锶钛氧化物外延薄膜。
6. In-situ observation of ultrafast 90° domain switching under application of an electric field in (100)/(001)-oriented tetragonal epitaxial Pb(Zr0.4Ti0.6)O3 thin films [O] . Yoshitaka Ehara, Shintaro Yasui, Takahiro Oikawa, -1

机译：（100）/（001）取向四方外延Pb（Zr0.4Ti0.6）O3薄膜在电场作用下超快90°域转换的原位观察
7. Strain-relaxed structure in (001)/(100)-oriented epitaxial Pb(Zr,Ti)O3 films grown on (100) SrTiO3 substrates by metal organic chemical vapor deposition [O] . Hiroshi Nakaki, Yong Kwan Kim, Shintaro Yokoyama, 2009

机译：通过金属有机化学气相沉积在（100）SRTIO3基板上生长的（001）/（100）的菌株弛豫结构（001）/（100）的外延PB（Zr，Ti）O3薄膜
8. Substrate effects on the structure and optical properties of epitaxial PbTiO(sub 3) thin films prepared by metal-organic chemical vapor deposition [R] . Foster, C. M., Li, Z., Bai, G. R., 1994

机译：衬底对金属有机化学气相沉积制备的外延pbTiO（sub 3）薄膜的结构和光学性质的影响

Strain-relaxed structure in (001)/(100)-oriented epitaxial Pb(Zr,Ti)O_3 films grown on (100) SrTiO_3 substrates by metal organic chemical vapor deposition

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