Absorption enhancement analysis of crystalline Si thin film solar cells based on broadband antireflection nanocone grating

摘要

1 μm thick Si solar cells based on nanocone grating (NCG) with height of 100-800 ran and period of 100, 500, and 800 nm are numerically investigated through reflectivities, absorption enhancement factors, absorption spectra, optical generation rates, ultimate efficiencies, and diffraction angles. Compared with the planar Si solar cell, absorption enhancement are observed in any solar cells with NCG surface. Their absorption enhancement mechanism varies with the incident wavelength range. When incident wavelength λ<500nm, antireflection of their front surface dominates the absorption enhancement behavior due to their stronger absorption coefficients. When 600nm>λ>500nm, even though the absorption enhancement is still dominated by antireflection of the front surface, cavity-resonance effect and guided-mode excitation induced by high order diffraction start to make contribution. When λ > 600 nm, the contribution of guided-mode excitation induced by lower-order diffraction becomes larger and larger once the diffraction angle is larger than its critical angle. For the structure with P= 100nm, high-order diffraction cut-off at the longer wavelength range is the main reason of its lower absorption enhancement and ultimate conversion efficiency. For P=800nm, the lower absorption enhancement and ultimate efficiency is also observed due to the high reflection loss and mode leakage induced by 1st order diffraction where its diffraction angle is lower than its critical angle. Higher absorption and ultimate conversion efficiencies are achieved in P = 500 nm due to the good balance between antireflection performance and guide-mode excitation induced by the high order diffraction is achieved. Moreover, such absorption enhancement is closely related with its height of NCG gratings. Reflection loss reduction, the interaction volume reduction between the incident light and Si material, and higher photon density in NCG structure coexists with H increasing, which results in absorption enhancement in P = 500 nm and P = 800 nm, but absorption reduction in P= 100 nm where high order diffraction cut-off. Based on these analysis, we do believe that high absorption and ultimate conversion efficiency should be achieved in NCG-based solar cells where both the lower reflection in short wavelength domain and guide-mode excitation induced by 1st and 2nd diffraction in longer wavelength domain can be achieved. According to this rule; the optimized structure is NCG with P = 559 nm and H = 500 nm, by which, the highest optical generation rate of 536.57 × 10~4W/cm~3 and ultimate efficiency of 28.132% are achieved. Such analysis should benefit the design of the thin film solar cells with nano-structured diffraction gratings.