Array of Cu_2O nano-columns fabricated by oblique angle sputter deposition and their application in photo-assisted proton reduction

摘要

Nano-columnar arrays of Cu_2O were grown by the oblique angle sputter deposition technique based on the self-shadowing principle. The as-grown nano-columnar samples are oriented along {111} direction, and they are highly transmitting in the visible range with a low reflectance. In this work, we show the photo-electrochemical activity of nano-columnar array of Cu_2O, which shows a higher (～25%) photocurrent density and a two-fold enhancement in the incident-to-photon conversion efficiency as compared to continuous thin film of Cu_2O in photo-assisted proton reduction type reaction. The improvement in electrochemical activity of nano-columnar Cu_2O photocathode can be attributed to the change in morphology, crystal structure, as well as electrical property, which shows a higher degree of band bending, increased donor carrier (e-) density and lower width of space charge region as revealed by capacitance measurements and Mott-Schottky analysis.