Determination of metal impurities in titanium dioxide using slurry sample introduction by axial viewing inductively coupled plasma optical emission spectrometry

摘要

A slurry sample introduction technique for the analysis of TiO_2 powders by axial viewing ICP-OES is reported. Relationships between stable slurries and the conditions, such as particle size, pH, dispersant and its amount, were experimentally investigated. Slurries were prepared by mixing the TiO_2 powder with the dispersant poly(acrylate amine) (NH_4PAA) and agitation in an ultrasonic bath to ensure good dispersion. The pH of the medium and amount of dispersant has been optimized. Impurities in TiO_2 were determined by an axial viewing ICP-OES spectrometer. As representatives, a Standard Reference Material 154 b of μm particle size TiO_2 and a nm particle size TiO_2 were selected and determined for micro and trace impurities. Analytical results obtained via slurry sample introduction were compared with those via nebulization of aqueous solutions prepared by acid digestion and fusion digestion. The determined results by slurry introduction were in good accordance with the stated values, which verified that the calibration curves could be established by aqueous standards.