Facile Synthesis of Monodispersed In_2O_3 Hollow Spheres and Application in Photocatalysis and Gas Sensing

摘要

Monodispersed, agglomerate-free In_2O_3 hollow spheres have been prepared via a simple synthetic route involving permeation and anchoring of In'+ ions with carbonyl groups of swollen commercial polymer beads in tetrachloroethylene solvent followed by thermal removal of the template cores in ambient air. The as-synthesized hollow spheres exhibit a narrow size distribution with tunable particle size (0.5-1.2 urn) and shell thickness (62-230 nm) over the process variables examined, i.e., InCl_3 precursor concentration (4.5×10~(-3)-6.7 × 10~(-2) M), reaction temperature (55℃-95℃), and reaction time (1-6 h). Kinetics calculation reveals that the formation of permeating In~(3+)-rich shell in the swollen template beads becomes energetically less favorable to proceed as the reaction time increases. This limits the maximum shell thickness attainable at the given process variables. The shell is nanoporous with a Horvath-Kawazoe (HK) pore size of ~3 nm, which remains essentially unchanged as the process variables alter. The In_2O3 hollow spheres with an increased Brunauer-Emmett-Teller (BET) surface area (up to 329 m~2/g) show an improved capability in photodegradation of aqueous methylene blue (MB) dye under UV exposure as well as an increased sensitivity for CO-gas detection. This metal-implantation scheme is general and can be extended to the synthesis of other hollow materials in various solvent liquids.