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Development of coating materials from liquid wax esters for wood top-based coating

机译:由液态蜡酯开发的涂料用于木质面漆

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摘要

Of late, UV-curable products are gaining attention in the wood industry because of the effectiveness and efficiency of this method. UV-curable surface coatings are widely used because of their excellent properties and because they are environmentally friendly products. In this study, immobilized Candida antarctica lipase B was used to catalyze formation of liquid wax esters, such as adipate esters, via a solvent-free process. The adipate esters formed were then used as UV-curable reactants in the wood coating formulations, consisting of epoxy acrylate, additives, and a photoinitiator. The performance of the products was evaluated by coating them onto glass tiles (using gel content, hardness, and scratch resistance tests) and wood panels (using adhesion, impact, and heat resistance tests). The coated film from this formulation performed well during the evaluation tests. The gel content exhibited more than 90% polymerization, while the pendulum hardness gave a value of 55.25%. Both analyses were significant in determining the effect of irradiation cycles. A scratch test was also carried out to verify the resistance of the coating. The maximum weight load which can be resisted by the wax esters formulation is 4.5 N.
机译:最近,由于这种方法的有效性和效率,可紫外线固化的产品在木材工业中越来越受到关注。可紫外线固化的表面涂料由于其优异的性能和环保产品而被广泛使用。在这项研究中,固定化的南极假丝酵母脂肪酶B用于通过无溶剂工艺催化液体蜡酯(例如己二酸酯)的形成。然后将形成的己二酸酯用作木材涂料配方中的UV固化反应物,该涂料由环氧丙烯酸酯,添加剂和光引发剂组成。通过将产品涂在玻璃砖(使用凝胶含量,硬度和耐刮擦性测试)和木板(使用附着力,耐冲击性和耐热性测试)上来评估产品的性能。该配方的涂膜在评估测试中表现良好。凝胶含量表现出超过90%的聚合,而摆硬度给出的值为55.25%。两项分析对确定辐照周期的影响均具有重要意义。还进行了划痕测试以验证涂层的电阻。蜡酯配方可抵抗的最大重量负荷为4.5N。

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  • 来源
    《JCT research》 |2011年第2期|p.229-236|共8页
  • 作者单位

    Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia,Laboratory of Industrial Biotechnology, Institute of Bioscience, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;

    Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;

    Malaysia Nuclear Agency, Bangi, 43000 Kajang, Selangor,Malaysia;

    Laboratory of Industrial Biotechnology, Institute of Bioscience, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;

    Laboratory of Industrial Biotechnology, Institute of Bioscience, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;

    Laboratory of Industrial Biotechnology, Institute of Bioscience, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    adipate esters; liquid wax esters; coating formulation; radiation curing; wood coating;

    机译:己二酸酯液态蜡酯;涂料配方;辐射固化木器涂料;

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