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Hydrogen production performance of 3-cell flat-tubular solid oxide electrolysis stack

机译:3槽扁平管状固体氧化物电解堆的制氢性能

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摘要

Flat-tubular solid oxide electrolysis cells have been manufactured with a ceramic inter-connector in a body to minimize the stack volume and eliminate metallic components. The NiO-YSZ supports are prepared by the extrusion method, and the other cell components, which included the electrolyte, air electrode, and ceramic interconnector, are fabricated by slurry coating methods. The active area of a single cell is 30 cm2, and the gas tightness of the stack is checked in the range below 2 bars. The effects of the operating conditions on the performance of a solid oxide electrolysis stack are investigated using electrochemical impedance spectroscopy and the I-V test. Consequently, it is confirmed that sufficient steam content stimulates the electrochemical splitting of water and decreases the activation energy for water electrolysis at a high temperature. In our 3-cell stack test, the hydrogen production rate is 4.1 lh~(-1), and the total hydrogen production was 144.321 during 37.1 h of operation.
机译:扁管式固体氧化物电解池已通过在主体中使用陶瓷互连器来制造,以最大程度地减少堆叠体积并消除金属成分。 NiO-YSZ载体是通过挤压法制备的,而其他的电池组件(包括电解质,空气电极和陶瓷互连器)则是通过浆涂法制备的。单个电池的有效面积为30 cm2,在2 bar以下的范围内检查电池组的气密性。使用电化学阻抗谱和I-V测试研究了操作条件对固体氧化物电解堆性能的影响。因此,证实了足够的蒸汽含量刺激了水的电化学分裂并降低了高温下水电解的活化能。在我们的3电池堆测试中,制氢速率为4.1 lh〜(-1),在37.1 h的运行中总制氢量为144.321。

著录项

  • 来源
    《International journal of hydrogen energy》 |2012年第1期|p.78-83|共6页
  • 作者单位

    Energy Materials Center, Korea Institute of Energy Research, 102 Gajeongro, Yuseonggu, Daejeon 305-343, Republic of Korea;

    Energy Materials Center, Korea Institute of Energy Research, 102 Gajeongro, Yuseonggu, Daejeon 305-343, Republic of Korea;

    Energy Materials Center, Korea Institute of Energy Research, 102 Gajeongro, Yuseonggu, Daejeon 305-343, Republic of Korea;

    Energy Materials Center, Korea Institute of Energy Research, 102 Gajeongro, Yuseonggu, Daejeon 305-343, Republic of Korea;

    Energy Materials Center, Korea Institute of Energy Research, 102 Gajeongro, Yuseonggu, Daejeon 305-343, Republic of Korea;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    high-temperature electrolysis; solid oxide electrolysis cells; hydrogen production; flat-tubular cells; all-ceramic stack;

    机译:高温电解固体氧化物电解槽制氢扁管细胞;全陶瓷堆栈;

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