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A swept-field aspiration condenser as an ion-mobility spectrometer

机译:扫场抽吸冷凝器作为离子迁移谱仪

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A method is presented for using a small, low-cost, extremely simple device as an ion-mobility spectrometer. The device is a planar first-order differential aspiration condenser as described by Puumalainen, but in this case the electric field is not kept constant but is swept in discrete nonuniform steps. The result is a characteristic I(V) curve that is a function of the ion-mobility density function of the gas sample flowing through the condenser. A discrete transform is introduced, based on the equations of Tammet describing the operation of aspiration condensers, that converts the I(V) curve into the ion-mobility density spectrum and vice versa. Both the device and the method are described in theoretical detail. The method is illustrated with computer simulations and experimental data using both a prototype aspiration condenser and a conventional drift tube ion-mobility spectrometer. The results suggest this method is an attractive alternative for ion-mobility gas analysis applications.
机译:提出了一种使用小型,低成本,极其简单的设备作为离子迁移谱仪的方法。该装置是如Puumalainen所述的平面一阶差分抽吸冷凝器,但是在这种情况下,电场不是保持恒定,而是以离散的不均匀步长扫掠。结果是特性I(V)曲线,该曲线是流经冷凝器的气体样品的离子迁移率密度函数的函数。基于描述吸附冷凝器操作的Tammet方程,引入了离散变换,该变换将I(V)曲线转换为离子迁移率密度谱,反之亦然。在理论上详细描述了该设备和方法。使用原型抽吸冷凝器和常规漂移管离子迁移谱仪对计算机仿真和实验数据进行了说明。结果表明,该方法是离子迁移气体分析应用的一种有吸引力的替代方法。

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