Phase Transition Temperatures and Piezoelectric Properties of (Bi1/2Na1/2)TiO3-and (Bi1/2K1/2)TiO3-Based Bismuth Perovskite Lead-Free Ferroelectric Ceramics

摘要

The phase transition temperatures and the dielectric, ferroelectric, and piezoelectric properties of bismuth perovskite lead-free ferroelectric ceramics such as (Bi1/2Na1/2)TiO3 (BNT)- and (Bi1/2Na1/2)TiO3 (BKT)-based solid solutions have been reviewed. According to the results obtained by our group, these ceramics can be considered as superior lead-free piezoelectric materials for reducing environmental damage. Perovskite-type ceramics appear to be suitable for actuator and high-power applications that require a large piezoelectric constant d33 and a high Curie temperature TC or a high depolarization temperature Td (> 200degC). In this paper, we summarize the relationship between phase transition temperatures and piezoelectric properties. In the case of the BNT-based solid solutions, the highest piezoelectric properties were obtained at the morphotropic phase boundary (MPB) between rhombohedral and tetragonal phases. However, d33 and Td were shown to have a tradeoff relationship. Considering the high Td and high d33, the tetragonal side of the MPB composition is suitable for piezoelectric actuator application. Meanwhile, the Qm values on the rhombohedral side of the MPB composition were better than those on the tetragonal side, and excellent high-power characteristics were obtained for Mn-doped BNT-(Bi1/2Na1/2)TiO3-BKT ternary systems with rhombohedral symmetry. BKT ceramics were prepared by the hot-pressing (HP) method, and their ferroelectric and piezoelectric properties were clarified. BKT ceramics doped with a small amount of Bi have a relatively high remanent polarization of Pr = 27.6 muC/cm2 and high piezoelectric properties (k33 = 0.40 and d33 = 101 pC/N). In addition, it was clarified that BKT ceramics have a high Td of approximately 300degC. The solid solution (1-x)BKT-xBaTiO3 (BKT-BT100x) exhibited a high Td of approximately 300degC at x > 0.4.