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Determination Of Residues Of Trichlorfon And Dimethoate On Guava Using Hplc

机译:高效液相色谱法测定番石榴中敌百虫和乐果的残留量

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摘要

A supervised trial was conducted in guava orchards during 2001 and 2002 to study residue dissipation rates of two organophos insecticides, trichlorfon and dimethoate at Kohat, NWFP, Pakistan. The insecticides were sprayed at recommended doses of 80 and 120 g a.i./100 1 water on the fruits of guava when the fruits were semi ripe. The treated guava fruits were randomly sampled in triplicates (2 kg per field replicate) at 0, 3, 7, 14, and 21 days intervals after insecticide application. The samples were extracted in ethyl acetate and were cleaned up through Florisil column with ethyl acetate as eluent. The cleaned up extracts were analyzed for residues by HPLC method. The residues were found to have half-lives of 2.8-3.3 days for dimethoate and 1.7-2.0 days for trichlorfon. Based on the dissipation pattern of the insecticide residues in relation to their respective prescribed maximum residue limits, withholding periods of 3 and 9 days are suggested for guava after treatment with dimethoate and trichlorfon.
机译:2001年至2002年在番石榴果园进行了一项有监督的试验,研究了巴基斯坦西北太平洋地区科哈特的两种有机磷杀虫剂敌百虫和乐果的残留消散率。当番石榴果实半熟时,以推荐的剂量80和120 g a.i./100 1水喷洒杀虫剂。施用杀虫剂后,在0、3、7、14和21天的间隔内,将处理过的番石榴果实一式三份(每场重复2千克)。将样品用乙酸乙酯萃取,并通过Florisil柱用乙酸乙酯作为洗脱剂进行纯化。通过HPLC方法分析纯化的提取物的残留物。发现残留的乐果半衰期为2.8-3.3天,敌百虫的半衰期为1.7-2.0天。根据杀虫剂残留相对于它们各自规定的最大残留限量的耗散模式,在乐果和敌百虫处理后,番石榴的保留期建议为3天和9天。

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