Application of surface complexation modeling on adsorption of uranium at water-solid interface: A review

摘要

Precise prediction of uranium adsorption at water-mineral interface is of great significance for the safe disposal of radionuclides in geologic environments. Surface complexation modeling (SCM) as a very useful tool has been extensively investigated for simulating adsorption behavior of metals/metalloids at water-mineral interface. Numerous studies concerning the fitting of uranium adsorption on various adsorbents using SCM are well documented, but the systematic and comprehensive review of uranium adsorption using various SCM is not available. In this review, we briefly summarized the rationale of SCM, including constant-capacitance-model (CCM), diffuse-layer-model (DLM), triple-layer-model (TLM); The recent progress in the application of SCM on the fitting of uranium adsorption towards metal (hydr) oxides, clay minerals and soil/sediments was reviewed in details. This review hopefully provides the beneficial guidelines for predicting the transport and fate of uranium in geologic environments beyond laboratory timescales. 0 2021 Elsevier Ltd. All rights reserved.