Optimization of C~1-Oxygenates for the Selective Oxidation of Methane in a Gas-Phase Reaction of CH_4-O_2-NO at Atmospheric Pressure

摘要

The optimization f C~1-oxygenates for the selective oxidation of CH_4 in the gas-phase reaction of CH_4-O_2-NO has been examined with kinetic models utilizing the software packages of ChEMKIN III. The variations of simulated selectivities of the products in the reactions reproduced Well the experimentally obtained values except for those of CH_3OH in a region of less than 10/100 CH_4 conversion.