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Synthesis, Characterization, and Evaluation of Evaporated Casting MWCNT/Chitosan Composite Membranes for Water Desalination

机译:蒸发浇铸MWCNT /壳聚糖复合膜水脱盐的合成,表征和评价

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Fresh water scarcity and pollution turn out to be a most serious issue throughout the world due to the rapid population growth. The application of nanomaterials (NMs) for the removal of pollutants from water has attracted significant attention. The nanofiltration membrane was fabricated through the evaporative casting (EC) method using multiwalled carbon nanotubes (MWCNT) and chitosan (CHIT) as the surfactant to enable water purification. The developed EC membrane properties were characterized in mechanical, surface charging (zeta potential), surface morphology, and hydrophobicity properties. Results demonstrated that incorporation of MWCNT and the biopolymers (chitosan) resulted in suitable developments in mechanical properties of the membrane. For example, the membrane has shown values for tensile strength (28?±?1?MPa), elongation (10.2?±?1.2%), Young’s modulus (1.2?±?0.1?GPa), and toughness of (1.9?±?0.2?J/g). When more significant changes were investigated on the surface morphology of the EC membrane, it was observed that the pores on the surface morphology of the EC membrane decreased as the evaporative casting method was used. Moreover, the permeability of the membrane towards water, inorganic salts, and pH effect on salt rejections was studied using the NF/RO system. These established nanocomposite membranes signify the promising candidates for fresh water desalination and elimination of organic impurities.
机译:由于人口迅速增长,淡水稀缺和污染成为全球最严重的问题。纳米材料(NMS)从水中取出污染物的应用引起了显着的关注。通过使用多壁碳纳米管(MWCNT)和壳聚糖(Chit)作为表面活性剂来制造纳滤膜(EC)方法,以使水纯化能够。发育的EC膜特征在机械,表面充电(Zeta电位),表面形态和疏水性性质中表征。结果表明,掺入MWCNT和生物聚合物(壳聚糖)导致膜的机械性能的适当发展。例如,膜示出了拉伸强度的值(28?±1?MPa),伸长(10.2?±1.2%),杨氏模量(1.2?±0.1?GPA),并且韧性(1.9?± ?0.2?J / g)。当对EC膜的表面形态进行了更大的变化时,观察到EC膜的表面形态上的孔隙随着所用蒸发浇铸方法而降低。此外,使用NF / RO系统研究了膜对水,无机盐和对盐抑制的pH对pH抵抗的渗透性。这些已建立的纳米复合膜意味着淡水脱盐和消除有机杂质的有希望的候选者。

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