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首页> 外文期刊>Science Advances >From force-responsive molecules to quantifying and mapping stresses in soft materials
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From force-responsive molecules to quantifying and mapping stresses in soft materials

机译:从力响应分子到柔软材料中的量化和映射应力

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Directly quantifying a spatially varying stress in soft materials is currently a great challenge. We propose a method to do that by detecting a change in visible light absorption. We incorporate a spiropyran (SP) force–activated mechanophore cross-linker in multiple-network elastomers. The random nature of the network structure of the polymer causes a progressive activation of the SP force probe with load, detectable by the change in color of the material. We first calibrate precisely the chromatic change in uniaxial tension. We then demonstrate that the nominal stress around a loaded crack can be detected for each pixel and that the measured values match quantitatively finite element simulations. This direct method to quantify stresses in soft materials with an internal force probe is an innovative tool that holds great potential to compare quantitatively stresses in different materials with simple optical observations.
机译:直接量化软材料中的空间变化的应力是目前是一个巨大的挑战。我们提出了一种通过检测可见光吸收的变化来做到这一点。我们在多网络弹性体中纳入了螺丝燕燕(SP)力激活的机械连接器。聚合物的网络结构的随机性质导致SP力探针的逐渐激活具有负载,通过材料的颜色变化可检测。我们首先校准单轴张力的色彩变化。然后,我们证明可以针对每个像素检测负载裂缝周围的标称应力,并且测量值匹配定量有限元模拟。这种直接方法为了用内力探针量化软材料中的柔软材料是一种创新工具,其具有与简单的光学观察不同材料中的定量应力的巨大潜力。

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