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An advanced and efficient Co3O4/C nanocomposite for the oxygen evolution reaction in alkaline media

机译:一种先进,高效的Co3O4 / C纳米复合材料,用于碱性介质中的氧释放反应

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The design of efficient nonprecious catalysts for the hydrogen evolution reaction (HER) or the oxygen evolution reaction (OER) is a necessary, but very challenging task to uplift the water-based economy. In this study, we developed a facile approach to produce porous carbon from the dehydration of sucrose and use it for the preparation of nanocomposites with cobalt oxide (Co _(3) O _(4) ). The nanocomposites were studied by the powder X-ray diffraction and scanning electron microscopy techniques, and they exhibited the cubic phase of cobalt oxide and porous structure of carbon. The nanocomposites showed significant OER activity in alkaline media, and the current densities of 10 and 20 mA cm ~(?2) could be obtained at 1.49 and 1.51 V versus reversible hydrogen electrode (RHE), respectively. The impedance study confirms favorable OER activity on the surface of the prepared nanocomposites. The nanocomposite is cost-effective and can be capitalized in various energy storage technologies.
机译:设计用于氢气释放反应(HER)或氧气释放反应(OER)的有效的非贵重催化剂是提高水基经济的必要但非常艰巨的任务。在这项研究中,我们开发了一种从蔗糖脱水生产多孔碳的简便方法,并将其用于制备氧化钴(Co _(3)O _(4))的纳米复合材料。通过粉末X射线衍射和扫描电子显微镜技术研究了纳米复合材料,它们显示出氧化钴的立方相和碳的多孔结构。纳米复合材料在碱性介质中显示出显着的OER活性,相对于可逆氢电极(RHE),在1.49和1.51 V时分别可获得10和20 mA cm〜(?2)的电流密度。阻抗研究证实了制备的纳米复合材料表面具有良好的OER活性。纳米复合材料具有成本效益,可以利用各种储能技术进行资本化。

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