Bis(μ2-N-methyl-N-phenyl-dithio-carbamato)-κ3S,S′:S;κ3S:S,S′-bis-[(N-methyl-N-phenyl-dithio-carbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis

Suwardi S.A.N.; Lee S.M.; Lo K.M.; Jotani M.M.; Tiekink E.R.T.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Bis(μ2-N-methyl-N-phenyl-dithio-carbamato)-κ3S,S′:S;κ3S:S,S′-bis-[(N-methyl-N-phenyl-dithio-carbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis

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Bis(μ2-N-methyl-N-phenyl-dithio-carbamato)-κ3S,S′:S;κ3S:S,S′-bis-[(N-methyl-N-phenyl-dithio-carbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis

机译：双（μ2-N-甲基-N-苯基-二硫代氨基甲酸酯）-κ3S，S'：S;κ3S：S，S'-双-[（N-甲基-N-苯基-二硫代氨基甲酸酯-κ2S，S ′）镉]：晶体结构和Hirshfeld表面分析

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The title compound, [Cd2(C8H8NS2)4], is a centrosymmetric dimer with both chelating and μ2-tridentate di-thio-carbamate ligands. The resulting S5 donor set defines a CdII coordination geometry inter-mediate between square-pyramidal and trigonal–bipyramidal, but tending towards the former. The packing features C—H?S and C—H?π inter-actions, which generate a three-dimensional network. The influence of these inter-actions, along with intra-dimer π–π inter-actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.

机译：标题化合物[Cd2（C8H8NS2）4]是具有螯合和μ2-三齿二硫代氨基甲酸酯配体的中心对称二聚体。由此产生的S5供体集定义了一个CdII配位几何，介于正方形和三角锥之间，但倾向于前者。堆积具有CHS和CHHπ相互作用，产生了三维网络。通过对Hirshfeld表面的分析，研究了这些相互作用的影响以及螯合环之间的二聚体内π-π相互作用。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第3期|共5页
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Suwardi S.A.N.; Lee S.M.; Lo K.M.; Jotani M.M.; Tiekink E.R.T.;
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1. An unprecedented binuclear cadmium di-thio-carbamate adduct: bis-[μ2-N-(2-hydroxy-eth-yl)-N-iso-propyl-carbamodi-thio-ato-κ3S:S,S′]bis-{[N-(2-hydroxy-eth-yl)-N-iso-propyl-carbamodi-thio-ato-κ2S,S′](3-{(1E)-[(E)-2-(pyridin-3-yl-methyl-idene)hydrazin-1-yl-idene]meth-yl}pyridine-κN)cadmium]} dihydrate [J] . Arman H.D., Poplaukhin P., Tiekink E.R.T. Acta Crystallographica Section E: Crystallographic Communications . 2016,第9期

机译：前所未有的双核二硫代氨基甲酸镉加合物：双-[μ2-N-（2-羟基-乙基-基）-N-异丙基-氨基甲酸-硫代-ato-κ3S：S，S'] bis- { [N-（2-羟基-乙基）-N-异丙基氨基甲酰氨基-硫代-κ2S，S']（3-{（1E）-[（E）-2-（吡啶-3-甲基-亚甲基）肼-1-基]甲基-}吡啶-κN）镉]二水合物
2. [N-Benzyl-N-(2-phenyl-eth-yl)di-thio-carbamato-κ2S,S′]tri-phenyl-tin(IV) and [bis-(2-meth-oxy-eth-yl)di-thio-carbamato-κ2S,S′]tri-phenyl-tin(IV): crystal structures and Hirshfeld surface analysis [J] . Mohamad R., Awang N., Kamaludin N.F., Acta Crystallographica Section E: Crystallographic Communications . 2016,第10期

机译：[N-苄基-N-（2-苯基-乙氧基）二硫代氨基甲酸酯-κ2S，S']三苯基-锡（IV）和[双-（2-甲基-氧基-乙氧基）二硫代氨基甲酸酯-κ2S，S']三苯基锡（IV）：晶体结构和Hirshfeld表面分析
3. Crystal structures and Hirshfeld surface analyses of bis-[N,N-bis-(2-meth-oxy-eth-yl)di-thio-carbamato-κ2S,S′]di-n-butyl-tin(IV) and [N-(2-meth-oxy-eth-yl)-N-methyl-dithio-carbamato-κ2S,S′]tri-phenyl-tin(IV) [J] . Mohamad R., Awang N., Kamaludin N.F., Acta Crystallographica Section E: Crystallographic Communications . 2018,第3期

机译：双-[N，N-双-（2-甲基-氧基-乙基-基）二硫代氨基甲酸酯-κ2S，S']二正丁基锡（IV）和[[ N-（2-甲基-氧基-乙基）-N-甲基-二硫代氨基甲酸酯-κ2S，S']三苯基-锡（IV）
4. Growth, crystal structure, Hirshfeld surface analysis, DFT and nonlinear optical studies of bis(4-methoxybenzylammonium) tetrachloridocadmate(II) [C] . S. Ananda, Hussien Ahmed Khamees, N. R. Bhavya, DAE Solid State Physics Symposium . 2020

机译：BIS（4-甲氧基苄基氨基铵）四氯丙酯（II）的生长，晶体结构，血频光学研究，DFT和非线性光学研究（II）
5. Part A. Chemical neutron activation analysis of aluminum in biological samples. Part B. Stereochemical consequences of chlorine substitution reactions with (2S,3S)dl-2-chloro-3-fluoropentane and (2S,3S)dl-3-chloro-2-fluoropentane in the gas, liquid and solid phase. [D] . Roman, Felix R. 1989

机译：A部分：生物样品中铝的化学中子活化分析。 B部分。在气相，液相和固相中与（2S，3S）dl-2-氯-3-氟戊烷和（2S，3S）dl-3-氯-2-氟戊烷的氯取代反应的立体化学结果。
6. Bis(μ2-N-methyl-N-phenyldithiocarbamato)-κ3SS′:S;κ3S:SS′-bis(N-methyl-N-phenyldithiocarbamato-κ2SS′)cadmium: crystal structure and Hirshfeld surface analysis [O] . Siti Aisyah Nabilah Suwardi, See Mun Lee, Kong Mun Lo, 2017

机译：双（μ2-N-甲基-N-苯基二硫氨基甲酸酯）-κ3SS：S;κ3S：SS-bis （N-甲基-N-苯基二硫氨基甲酸酯-κ2SS）镉：晶体结构和Hirshfeld表面分析
7. Bis(μ2-N-methyl-N-phenyldithiocarbamato)-κ3S,S′:S;κ3S:S,S′-bis(N-methyl-N-phenyldithiocarbamato-κ2S,S′)cadmium: crystal structure and Hirshfeld surface analysis [O] . Siti Aisyah Nabilah Suwardi, Lee See Mun *, Lo Kong Mun *, 2017

机译：Bis（μ2-N-甲基-N-苯基二硫代氨基甲酸酯）-κ3S，S'：S;κ3S：S，S'-bis （N-甲基-N-甲基-N-苯基二硫代氨基甲酸酯-κ2S，S'）镉：晶体结构和Hirshfeld表面分析
8. Chiral Recognition in Molecular and Macromolecular Pairs of Liquid Crystals of (2R, 3S)- and (2S, 3S)-2-Fluoro-3-methylpentyl-4'-(11-Vinyloxyundecanyloxy)biphenyl-4- carboxylate Diastereomers. [R] . Percec, V., Oda, H., Rinaldi, P. L., 1994

机译：（2R，3s） - 和（2s，3s）-2-氟-3-甲基戊基-4' - （11-乙烯氧基十一烷氧基）联苯-4-羧酸非对映异构体的分子和大分子液晶对的手性识别。

Bis(μ2-N-methyl-N-phenyl-dithio-carbamato)-κ3S,S′:S;κ3S:S,S′-bis-[(N-methyl-N-phenyl-dithio-carbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis

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