A Stereospecific Synthesis of (+)-2-Epideoxymannojirimycin and (2R,3R,4R,5R)-3,4,5-Trihydroxypipecolic Acid

Ki Hun Park

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A Stereospecific Synthesis of (+)-2-Epideoxymannojirimycin and (2R,3R,4R,5R)-3,4,5-Trihydroxypipecolic Acid

机译：（+）-2-Epideoxymannojirimycin和（2R，3R，4R，5R）-3,4,5-三羟基胡椒酸的立体定向合成

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摘要

2-Epideoxymannojirimycin 1 and (2R,3R,4R,5R)-3,4,5-trihydroxypipecolic acid 2 were prepared starting from D-glucosamic acid as a chiral educt. Key transformations were selective removal of the terminal isopropylidene group and intramolecular cyclization by SN2 reaction.

机译：从D-氨基葡萄糖酸作为手性离析物制备2-环氧脱氧甘露糖霉素1和（2R，3R，4R，5R）-3，4，5-三羟基哌酸2。关键的转化是通过SN2反应选择性除去末端异亚丙基和分子内环化。

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《Bulletin of the Korean Chemical Society》 |1995年第10期|共页
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Ki Hun Park;
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中图分类化学;
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A Stereospecific Synthesis of (+)-2-Epideoxymannojirimycin and (2R,3R,4R,5R)-3,4,5-Trihydroxypipecolic Acid

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