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Mechanical Properties Thermoplastic Laminates of Polycarbonate-Polyetherimide Blend with Glass Fibers

机译:机械性能聚碳酸酯-聚醚酰亚胺与玻璃纤维共混物的热塑性层压板

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Thermoplastic Laminates of Polycarbonate (PC)/Polyetherimide (PEI) blend with glass fibers were prepared by solution blending of PC & PEI in different ratio of 100/0, 95/5, 90/10, 85/15 and 80/20 using Dichloromethane as solvent followed by applying the resulting blend solutions over the cut sheet size (30 x 25 cm) of woven mat glass fibers & dried overnight, then stacked up 12 flies of the impregnates and consolidated in a hot press at 300°C and 3-4 ton (30 kg/cm?) pressure for a duration of one hour & cooled. The laminates of PC/PEI blends/woven mat glass fibers were studied for their mechanical properties viz: Tensile, Flexural, Impact and Inter Laminar Shear Strength and thermo-mechanical properties viz: TGA, DSC, DMA as well as examination of morphology by SEM. The mechanical properties of laminates of PC/PEI blends/woven mat glass fibers shows an increasing trend in Inter Laminar Shear Strength, Tensile and Flexural Strength upto 20% PEI while Impact Strength shows an increase upto 10% and decreases while the percentage of PEI increases. Glass transition temperature of the laminates increases with increasing content of PEI and the degradation kinetics of TGA reveal that the decomposition temperature decreases with increasing content of PEI. DMA of laminates shows that the thermo-mechanical properties get improved at a higher temperature with the presence of PEI.
机译:通过使用二氯甲烷以100 / 0、95 / 5、90 / 10、85 / 15和80/20不同比例的PC和PEI溶液共混制备聚碳酸酯(PC)/聚醚酰亚胺(PEI)与玻璃纤维的热塑性层压板作为溶剂,然后将所得共混物溶液涂布到切割的片状玻璃纤维毡上(30 x 25厘米)并干燥过夜,然后堆叠12股浸渍剂并在300°C的热压中固结3- 4吨(30千克/厘米2)压力持续1小时并冷却。研究了PC / PEI共混物/机织玻璃纤维层压板的机械性能,即:拉伸,挠曲,冲击和层间剪切强度和热机械性能,即:TGA,DSC,DMA以及通过SEM观察形态。 PC / PEI共混物/机织玻璃纤维层压板的机械性能的层间剪切强度,拉伸强度和挠曲强度显示出高达20%PEI的增长趋势,而冲击强度显示出高达10%的增幅并降低,而PEI的百分比增加。层压材料的玻璃化转变温度随PEI含量的增加而增加,TGA的降解动力学表明,分解温度随PEI含量的增加而降低。层压板的DMA显示,在PEI的存在下,高温下的热机械性能得到改善。

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