Copper-Nickel-Carbon nanocomposite coatings are synthesized by the sequential sputter deposition of carbon (C) and a copper-nickel (Cu 1- x Ni x ) alloy. A distinct transition occurs as the Ni content ( x ) is increased from 0 to 1.00 during the Cu 1- x Ni x alloy deposition. The coating morphology changes from a dispersion of metallic Cu-particles in a C matrix to a well-defined nanolaminate structure. Between these morphological forms, a new prototype nanocomposite is produced at a Ni concentration ( x ) of 0.1-0.4 with the appearance of an interpenetrating matrix structure of C and Cu(Ni). This morphological structure has both a high 24-27 GPa hardness ( H ) and a low elastic modulus ( E ) of 144-169 GPa that results in a record high values of H / E at 1/6 and a H 3 / E 2 at 0.67-0.69 GPa in a novel compliant and hard coating.
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机译:铜-镍-碳纳米复合涂层是通过碳(C)和铜-镍(Cu 1-x Ni x)合金的顺序溅射沉积而合成的。在Cu 1-x Ni x合金沉积过程中,随着Ni含量(x)从0增加到1.00,发生了明显的转变。涂层的形态从金属铜颗粒在C基质中的分散转变为轮廓分明的纳米层状结构。在这些形态之间,Ni浓度(x)为0.1-0.4时产生了一种新的原型纳米复合材料,并出现了C和Cu(Ni)互穿的基质结构。这种形态结构既具有24-27 GPa的高硬度(H),又具有144-169 GPa的低弹性模量(E),这导致H / E值达到创纪录的1/6和H 3 / E 2在0.67-0.69 GPa的压力下具有新颖的柔韧性和硬涂层。
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