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Critical Effects of Smoking Parameters on the Levels of Polycyclic Aromatic Hydrocarbons in Traditionally Smoked Fish and Meat Products in Finland

机译:吸烟参数对芬兰传统熏制鱼和肉制品中多环芳烃含量的关键影响

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Eighty fish products and 62 meat products were sampled and analysed in Finland, in the year of 2012 for four marker polycyclic aromatic hydrocarbons (PAH4) with an accredited gas chromatography-tandem mass spectrometry method. In general, the determined PAH4 levels were relatively low and below the maximum levels. The mean concentrations of smoked fish samples were 0.7 μg·kg−1 for benzo[a]pyrene and 3.9 μg·kg−1 for the PAH4 sum, whereas in smoked meat samples, mean benzo[a]pyrene and PAH4 sum levels were 2.2 μg·kg−1 and 11 μg·kg−1, respectively. However, PAH4 sum concentrations ranged from not detected to 200 µg·kg−1 particularly among meat products, underlining the importance of controlling the smoking process. In this study, the effect of selected smoking parameters, i.e., smoking technique (direct/indirect), smoking time (less than five hours/more than five hours), smoke generation temperature (optimisedonoptimised), and the distance (less than five metres/more than five metres) between the food and the smoke source, confirmed the linkage between the smoking factors and the PAH4 levels formed in fish and meat products. As guidance for a safe smoking process, it was demonstrated that an indirect smoking technique, a shorter smoking time, an optimised smoke generation temperature, and a longer distance from the smoke source generated lower PAH concentrations in food products. However, while a shorter smoking time generated lower PAH levels in meat products, the levels in fish products were unexpectedly higher than in those smoked for a longer time. Other factors, such as the smoking type (cold smoking/warm or hot smoking) and the fish size, may have affected this result.
机译:2012年,芬兰采用了公认的气相色谱-串联质谱法对80种鱼产品和62种肉产品进行了采样和分析,分析了四种标记多环芳烃(PAH4)。通常,测定的PAH4水平相对较低,低于最大水平。熏制鱼类样品中苯并[a] py的平均浓度为0.7μg·kg-1,PAH4总和为3.9μg·kg-1,而熏制肉类样品中苯并[a] py和PAH4的总水平为2.2 μg·kg-1和11μg·kg-1。但是,尤其是在肉制品中,PAH4的总浓度范围从未检测到200µµg·kg-1,这突出了控制吸烟过程的重要性。在这项研究中,选定吸烟参数的影响,即吸烟技术(直接/间接),吸烟时间(少于5小时/超过5小时),烟雾产生温度(最优化/未最优化)和距离(低于食物和烟源之间的距离为5米/超过5米),这证实了吸烟因素与鱼和肉类产品中形成的PAH4水平之间存在关联。作为安全吸烟过程的指导,已证明间接吸烟技术,更短的吸烟时间,最优化的烟雾生成温度以及与烟源的距离更长,可降低食品中的PAH浓度。然而,虽然较短的吸烟时间在肉制品中产生的PAH含量较低,但是鱼制品中的PAH含量却比长时间吸烟的鱼类更高。其他因素,例如吸烟类型(冷/热或热吸烟)和鱼的大小,可能会影响此结果。

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