Metodologias eletroanalíticas para a determina??o de herbicidas triazínicos por voltametria de onda quadrada e técnicas de deconvolu??o

摘要

This work describes the development of electroanalytical methodologies for the determination of atrazine, ametrine and simazine by square wave voltammetry on a mercury electrode. For pure atrazine and pure ametrine, the detection limits (DL) were 3.7 and 4.3 μg L-1, respectively, while they increased to 4.8 and 6.5 μg L-1 in the presence of 3.0 x 10-6 mol L-1 of the other component (a mathematical deconvolution program was used in the mixture cases). The voltammetric response for simazine could not be separated from that of atrazine and measurements were carried out only in pure simazine solutions (DL: 7.5 μg L-1).