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Tin oxide quantum dots decorated graphitic carbon nitride for enhanced removal of organic components from water: Green process

机译:氧化锡量子点装饰有石墨氮化碳,可增强从水中去除有机成分的作用:绿色工艺

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Quantum dots being zero dimensional and much smaller in size have special properties and density of states that can be exploited for various commercial applications relative to bulk counterparts. Specific characteristics of semiconductor metal oxides are tunable by controlling size, composition, shape and combination with metal or non-metal component. Current study focus the facile fabrication of SnO2qunatum dots decorated on 2-D material g-C3N4. Using a simple route SnO2/g-C3N4nanonybrids have been prepared in pure phase with size of SnO2are found in Quantum dots (QDs) range (2–10?nm) and applied to target the enhanced photocatalytic activity. The structural and morphological features of SnO2/g-C3N4nanohybrids were successfully conducted by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM), respectively. The photocatalytic performance of the SnO2/g-C3N4nanohybrids was evaluated for the degradation of Rhodamine-B (RhB) solution, and an enhanced activity is observed attesting synergetic effect between SnO2QDs and exfoliated g-C3N4layers. It is found that the ratio of SnO2to g-C3N4in the hybrids critically affects the photocatalytic activity, with ratio 1:2 showing best performance. The present study offers simple and facile method to highlight the promising contribution of SnO2/g-C3N4hybrid in eliminating waste water organic contaminants and environmental issues.
机译:零维且尺寸小得多的量子点具有特殊的性质和状态密度,相对于整体同类物,量子点可用于各种商业应用。可以通过控制尺寸,组成,形状以及与金属或非金属成分的组合来调节半导体金属氧化物的特定特性。当前的研究集中于在二维材料g-C3N4上装饰SnO2量子点的简便制造。使用简单的方法,可以制备纯相中的SnO2 / g-C3N4纳米杂物,其SnO2的大小在量子点(QDs)范围(2-10?nm)内,并用于增强光催化活性。通过X射线衍射(XRD),X射线光电子能谱(XPS),扫描电子显微镜(SEM)和透射电子显微镜(TEM)分别成功地完成了SnO2 / g-C3N4纳米杂化物的结构和形态特征。评估了SnO2 / g-C3N4纳米杂化物的光催化性能对罗丹明B(RhB)溶液的降解,并且观察到活性增强,证明了SnO2QD与剥离的g-C3N4层之间的协同作用。发现在杂化物中SnO2与g-C3N4的比例严重影响光催化活性,比例为1:2表现出最佳性能。本研究提供了一种简单易行的方法,以突出显示SnO2 / g-C3N4杂化物在消除废水中有机污染物和环境问题方面的有前途的贡献。

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