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Effect of Chemically Treated Leather Shaving Addition on characteristics and microstructure of OPC mortars

机译:化学处理的皮革剃刮对OPC砂浆特性和微观结构的影响

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摘要

The growing concern with environmental issues in tanneries and the search for a technological solution to their wastes are evaluated in this study. The leather shaving was chemically treated aiming the immobilization of the chromium ion on ordinary Portland cement (OPC) matrix. Cementitious mortars were obtained by adding different proportions of waste treated solutions (5 and 10% compared to the cement mass) and after 28 days, the samples were evaluated in relation to their physical properties, axial compressive strength and, for the most promising compositions, microstructural characterization analyses tests were realized. Results showed that the alternatives used for the pretreatment were effective for the leather shaving dissolution; but the results analysis describes little change in pH values when the treated waste is added in three different media. The best axial compressive strength after 28 days age were obtained by addition of diluted phosphoric acid solution at low concentration, although this addition minimize the Portlandite formation and favor the calcium phosphate formation.
机译:在这项研究中,对制革厂对环境问题的日益关注以及寻找其废物的技术解决方案进行了评估。皮革剃须经过化学处理,旨在将铬离子固定在普通波特兰水泥(OPC)基质上。通过添加不同比例的废液(相对于水泥质量为5%和10%)来获得水泥砂浆,并在28天后对样品的物理性能,轴向抗压强度以及最有希望的成分进行了评估,实现了微结构表征分析测试。结果表明,用于预处理的替代方法对于溶解皮革中的剃须有效。但是结果分析表明,将处理后的废物添加到三种不同的介质中后,pH值几乎没有变化。通过添加低浓度的稀磷酸溶液,可获得28天龄后的最佳轴向抗压强度,尽管这种添加可以最大程度地减少硅酸盐的形成并有利于磷酸钙的形成。

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