Extraction and DFT Study on the Complexation of the TRIS⁺ Cation with a Hexaarylbenzene-Based Receptor

摘要

From extraction experiments and γ-activity measurements, the exchange extraction constant corresponding to the equilibrium TRIS+(aq) + 1.Cs+(nb) ? 1.TRIS+(nb) + Cs+(aq) taking place in the two–phase water–nitrobenzene system (TRIS+ = (HOCH2)3C–NH3 +, 1 =