Carbon nanotube-polymer interactions in nanocomposites: A review

摘要

The interaction between carbon nanotubes and polymers is critically reviewed. The interfacial characteristics directly influence the efficiency of nanotube reinforcements in improving mechanical, thermal, and electrical properties of the polymer nanocomposite. In this review, various techniques of interaction measurements, including experimental and modelling studies, are described. From the experimental approaches, wetting, spectroscopy and probe microscopy techniques are discussed in detail. Molecular dynamics, coarse grain simulation and density functional theory are also explained as the main modelling approaches in interaction measurement studies. Different methods of interaction improvement, mainly categorized under covalent and noncovalent interactions, are described afterwards. Modelling predictions of nanocomposite properties, such as Young's modulus, are compared with the experimental results in the literature and the challenges are discussed. Finally, it is concluded that an optimum carbon nanotube-polymer interaction is a key factor towards reaching the full potential of carbon nanotubes in nanocomposites.