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Synthesis, Proton Conductivity and Humidity sensing Property of γ -Type Zirconium Hydrogen Phosphate, Zr(HPO_4)_2 · 2H_2O

机译:γ-型磷酸氢锆Zr(HPO_4)_2·2H_2O的合成,质子电导率和湿敏性

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摘要

A γ-type of layered zirconium hydrogen phosphate, Zr(HPO_4)_2 · 2H_2O (γ-ZrP), was synthe- sized under hydrothermal conditions and characterized by powder X-ray diffraction and thermo- gravimetric analysis. The temperature dependence of the proton conductivity in γ-ZrP was investi- gated in a temperature range of 23~413 deg. C by ac impedance spectroscopy. The variation of the conductivity with water loss and phase transitions was observed.
机译:在水热条件下合成了一种γ型层状磷酸氢锆Zr(HPO_4)_2·2H_2O(γ-ZrP),并通过粉末X射线衍射和热重分析对其进行了表征。研究了γ-ZrP中质子电导率的温度依赖性,温度范围为23〜413度。 C通过交流阻抗谱。观察到电导率随失水和相变的变化。

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