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Aqueous solubilization of photochromic compounds by bile salt aggregates

机译:胆盐聚集体将光致变色化合物溶于水

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摘要

Bile salts form aggregates in aqueous solutions which were shown to efficiently solubilize aqueous insoluble photochromic compounds. Photochromic switching was observed for a spiro-pyran and a diarylethene. In the case of the spiropyran, the incorporation into the bile salt aggregate led to improved hydrolytic stability and changes in thermal rate constants.
机译:胆汁盐在水溶液中形成聚集体,其显示出可有效溶解水性不溶性光致变色化合物。对于螺-吡喃和二芳基乙烯观察到光致变色转换。在螺吡喃的情况下,掺入胆汁盐聚集物中导致改善的水解稳定性和热速率常数的变化。

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  • 来源
    《Chemical Communications》 |2010年第11期|1941-1943|共3页
  • 作者单位

    Department of Chemistry, University of Victoria, PO Box 3065,Victoria, BC, Canada V8W 3V6;

    Department of Chemistry, University of Victoria, PO Box 3065,Victoria, BC, Canada V8W 3V6;

    Xerox Research Centre of Canada, 2660 Speakman Drive,Mississauga, ON, Canada L5K 2L1 Institute of Materials Research & Engineering (IMRE), 3 Research Link, Singapore 117602;

    Xerox Research Centre of Canada, 2660 Speakman Drive,Mississauga, ON, Canada L5K 2L1;

    Department of Chemistry, University of Victoria, PO Box 3065,Victoria, BC, Canada V8W 3V6;

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  • 入库时间 2022-08-17 13:23:32

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