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The synthesis and structure of chiral enamine N-oxides

机译:手性烯胺N-氧化物的合成与结构

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摘要

Chiral enamine N-oxides have been synthesised by a diastereoselective intermolecular reverse-Cope cycloaddition reaction between chiral hydroxylamines and activated acetylenes. Their structures have been investigated by NMR, X-ray crystallography and computational methods.
机译:通过手性羟胺和活化的乙炔之间的非对映选择性分子间反向Cope环加成反应合成了手性烯胺N-氧化物。它们的结构已通过NMR,X射线晶体学和计算方法进行了研究。

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  • 来源
    《Chemical Communications》 |2014年第55期|7336-7339|共4页
  • 作者单位

    Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, Crown St, Liverpool L69 7ZD, UK;

    Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, Crown St, Liverpool L69 7ZD, UK;

    Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, Crown St, Liverpool L69 7ZD, UK;

    Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, Crown St, Liverpool L69 7ZD, UK;

    Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, Crown St, Liverpool L69 7ZD, UK;

    Robert Robinson Laboratories, Department of Chemistry, University of Liverpool, Crown St, Liverpool L69 7ZD, UK;

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