Metamagnetic behaviour in a new Cu(Ⅱ)Re(Ⅳ) chain based on the hexachlororhenate(Ⅳ) anion

Jose Martinez-Lillo; John Kong; Wdeson P. Barros; Juan Faus; Miguel Julve; Euan K. Brechin

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Metamagnetic behaviour in a new Cu(Ⅱ)Re(Ⅳ) chain based on the hexachlororhenate(Ⅳ) anion

机译：六氯r酸根（Ⅳ）阴离子在新的Cu（Ⅱ）Re（Ⅳ）链中的超磁行为

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A new chloro-bridged heterobimetallic Cu(Ⅱ)Re(Ⅳ) chain of formula {Cu(pyim)(Him)_2ReCl_6}_n MeCN (1·MeCN) has been prepared and magnetostructurally characterised. Compound 1 is the first example of the [Re~ⅣCl_6]~(2-) anion acting as a metalloligand towards a paramagnetic metal ion.

机译：制备了新的式{Cu（pyim）（Him）_2ReCl_6} _n MeCN（1·MeCN）的氯桥杂双金属Cu（Ⅱ）Re（Ⅳ）链，并对其磁结构进行了表征。化合物1是[Re〜ⅣCl_6]〜（2-）阴离子的第一个例子，它是对顺磁性金属离子的金属配体。

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《Chemical Communications》 |2014年第44期|5840-5842|共3页
作者
Jose Martinez-Lillo; John Kong; Wdeson P. Barros; Juan Faus; Miguel Julve; Euan K. Brechin;
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作者单位

EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road,EH9 3JJ, Edinburgh, Scotland, UK;

EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road,EH9 3JJ, Edinburgh, Scotland, UK;

Instituto de Ciencia Molecular (ICMol), Universitat de Valencia,C/ Catedratico Jose Beltran 2, 46980, Paterna, Valencia, Spain;

Instituto de Ciencia Molecular (ICMol), Universitat de Valencia,C/ Catedratico Jose Beltran 2, 46980, Paterna, Valencia, Spain;

Instituto de Ciencia Molecular (ICMol), Universitat de Valencia,C/ Catedratico Jose Beltran 2, 46980, Paterna, Valencia, Spain;

EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road,EH9 3JJ, Edinburgh, Scotland, UK;

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入库时间 2022-08-17 13:15:52

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1. Magneto-structural correlations in a family of (ReCuII)-Cu-IV chains based on the hexachlororhenate(IV) metalloligand [J] . Pedersen Anders H., Julve Miguel, Martinez-Lillo Jose, Dalton transactions: An international journal of inorganic chemistry . 2017,第46期

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Metamagnetic behaviour in a new Cu(Ⅱ)Re(Ⅳ) chain based on the hexachlororhenate(Ⅳ) anion

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