Reactivity of a fac-ReCl(α-diimine)(CO)_3 complex with an NAD~+ model ligand toward CO_2 reduction

摘要

The reactivity of a rhenium complex containing an NAD~+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO_2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph_3C~+.