Transition Metal Complexes with Sterically Demanding Ligands, 3.~1 Synthetic Access to Square-Planar Terdentate Pyridine-Diimine Rhodium(I) and Iridium(I) Methyl Complexes: Successful Detour via Reactive Triflate and Methoxide Complexes

Stefan Nuckel; Peter Burger

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Transition Metal Complexes with Sterically Demanding Ligands, 3.~1 Synthetic Access to Square-Planar Terdentate Pyridine-Diimine Rhodium(I) and Iridium(I) Methyl Complexes: Successful Detour via Reactive Triflate and Methoxide Complexes

机译：具有立体需求的配体的过渡金属配合物，以3〜1合成途径合成方平面的叔丁基吡啶-二胺铑（I）和铱（I）甲基配合物：通过反应性三氟甲磺酸盐和甲氧化物配合物成功绕道而行

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The synthesis of novel square-planar, terdentate, aryl-substituted pyridine-diimine Rh(I) and Ir(I) chloro complexes from the free ligands and the bis(#mu#-chloro) ethylene-bridged dimers [(C_2H_4)RhIrCl]_2 is reported.

机译：由游离配体和双（＃mu＃-氯）乙烯桥联二聚体[（C_2H_4）RhIrCl合成新颖的方形平面，四齿，芳基取代的吡啶-二亚胺Rh（I）和Ir（I）氯配合物已报告] _2。

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《Organometallics》 |2001年第21期|共15页
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Stefan Nuckel; Peter Burger;
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中图分类有机化学;有机质材料;
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1. Transition Metal Complexes with Sterically Demanding Ligands, 3.~1 Synthetic Access to Square-Planar Terdentate Pyridine-Diimine Rhodium(I) and Iridium(I) Methyl Complexes: Successful Detour via Reactive Triflate and Methoxide Complexes [J] . Stefan Nuckel, Peter Burger Organometallics . 2001,第21期

机译：具有立体需求的配体的过渡金属配合物，以3〜1合成途径合成方平面的叔丁基吡啶-二胺铑（I）和铱（I）甲基配合物：通过反应性三氟甲磺酸盐和甲氧化物配合物成功绕道而行
2. Transition-Metal Complexes with Sterically Demanding Ligands: Facile Thermal Intermolecular C-H Bond Activation in a Square-Planar Ir~I Complex [J] . Stefan Nuckel, Peter Burger Angewandte Chemie . 2003,第14期

机译：具有立体需求的配体的过渡金属配合物：方平面Ir〜I配合物中的便捷热分子间C-H键活化
3. Organic Syntheses via Transition Metal Complexes. 109. Transfer of Carbene Ligands from Group VI Metals to Rhodium as the Key Step of a Rhodium-Catalyzed Reactivity Enhancement of Fischer Carbene Complexes [J] . Inigo Gottker-Schnetmann, Rudolf Aumann Organometallics . 2001,第2期

机译：通过过渡金属络合物的有机合成。 109.将碳配体从第六族金属转移到铑中，这是铑催化费希尔碳烯配合物增强反应性的关键步骤
4. Iridium Complexes with Terdentate Ligands: Cyclometalated vs. Polypyridine Analogues; Hybrid vs. 'Pure' DFT [C] . Marcella Ravaglia, Marco Garavelli, Matthew Poison, International Conference of Computational Methods in Sciences and Engineering 2007(ICCMSE 2007); 20070925-30; Corfu(GR) . 2007

机译：具有齿状配体的铱配合物：环金属化与聚吡啶类似物；混合与“纯” DFT
5. Sterically demanding ligands and their effect on the structure and reactivity of main group metal complexes. [D] . Chmely, Stephen Christopher. 2010

机译：立体要求高的配体及其对主族金属配合物的结构和反应性的影响。
6. Rhodium and Iridium Mediated C-H and O-H Bond Activation of Two Schiff Base Ligands: Synthesis Characterization and Catalytic Properties of the Organometallic Complexes [O] . Poulami Sengupta, Rituparna Das, Papu Dhibar, 2021

机译：铑和铱介导的C-H和O-H键活化两种席夫碱配体：有机金属配合物的合成表征和催化性能
7. Ligand substitution reactions in new square-planar iridium, rhodium and platinum complexes containing a potentially terdentate C,N,N′ ligand system; crystal structure of Ir{C6H4CH2N(Me)CH2CH2NMe2-2-C,N,N′}(cod)(cod = cycloocta-1,5-diene) [O] . Ingrid C. M. Wehman-Ooyevaar, G. Marc Kapteijn, David M. Grove, 1994

机译：新型平面平面铱，铑和铂复合物中的配体取代反应，含有潜在的Terdentate C，N，N'配体系统; IR {C6H4CH2N（ME）CH2CH2NME2-2-C，N，N'}（COD）的晶体结构（COD = CycloCTA-1,5-二烯）

Transition Metal Complexes with Sterically Demanding Ligands, 3.~1 Synthetic Access to Square-Planar Terdentate Pyridine-Diimine Rhodium(I) and Iridium(I) Methyl Complexes: Successful Detour via Reactive Triflate and Methoxide Complexes

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