Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systems

Andrei N. Vedernikov; Kenneth G. Caulton

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Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systems

机译：铜-[2.1.1]-（2,6）-吡啶并菲-PhINTs系统中的易烷烃官能化

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Mild catalytic dehydrogenation of cycloalkanes (cyclo-C_5H_(10), cyclo-C_6H_(12), cyclo-C_8H_(16)) and aziridination of resulting olefins is reported with PhINTs and copper-[2.1.1]-(2,6)-pyridino-phane (L) complexes LCuX_n (n = 1, 2; X = Cl, OTf) "activated" with NaBAr~F_4 in dichloromethane solution.

机译：据报道，用PhINTs和铜-[2.1.1]-（2,6）对环烷烃（环-C_5H_（10），环-C_6H_（12），环-C_8H_（16））进行轻度催化脱氢和所得烯烃的叠氮化。 -吡啶基-phane（L）与NaCur_F_4在二氯甲烷溶液中“活化”的LCuX_n（n = 1，2; X = Cl，OTf）络合物。

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《Chemical Communications》 |2004年第2期|p.162-163|共2页
作者
Andrei N. Vedernikov; Kenneth G. Caulton;
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Department of Chemistry, Indiana University, Bloomington, Indiana 47405;

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正文语种 eng
中图分类化学;
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1. [2.1.1]-(2,6)-pyridinophane(L)-controlled alkane C-H bond cleavage: (L)PtMe2H+ as a precursor to the geometrically "tense'' transient (L)PtMe+ [J] . Vedernikov AN., Huffman JC., Caulton KG. New Journal of Chemistry . 2003,第4期

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2. FACILE HYDRODEHALOGENATION WITH H-2 AND PD/C CATALYST UNDER MULTIPHASE CONDITIONS .3. SELECTIVE REMOVAL OF HALOGEN FROM FUNCTIONALIZED ARYL KETONES .4. ARYL HALIDE-PROMOTED REDUCTION OF BENZYL ALCOHOLS TO ALKANES [J] . Marques CA., Tundo P., Selva M. The Journal of Organic Chemistry . 1995,第8期

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3. An Electron-Poor Dioxa-[2.1.1]-(2,6)-pyridinophane Ligand and Its Application in Cu-Catalyzed Olefin Aziridination [J] . Yang Fan, Ruan Jiaheng, Zavalij Peter Y., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第22期

机译：电子差的二氧化硅 - [2.1.1] - （2,6） - 吡啶烷烷配体及其在Cu催化的烯烃亚己酰胺中的应用
4. RAFT Dispersion Polymerization in Non-Polar Solvents: Facile Production of Block Copolymer Spheres, Vesicles and Thermo-responsive Worms in n-Alkanes [C] . Matthew J. Derry, Lee A. Fielding, Jacob A. Lane National American Chemical Society Meeting . 2014

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5. Engineering a homogeneous alkane conversion catalyst: A porphyrin based approach to alkane activation and functionalization. [D] . Nelson, Andrew P. 2004

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6. Draft Genome Sequence of a Medium- and Long-Chain n-Alkane-Degrading Bacterium Tsukamurella tyrosinosolvens Strain PS2 with Two Genetic Systems for Alkane Degradation [O] . Valeriya A. Romanova, Eugenia A. Boulygina, Maria N. Siniagina, 2019

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机译：在多相条件下使用HP和Pd / C催化剂轻松进行加氢脱卤。 3.从功能化的芳族酮中选择性除去卤素。 4.芳基卤化物促进的苄醇还原为烷烃
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机译：顺式 - 顺式 - 2,6-二氧代氢-1H，5H-二咪唑（4,5-b：4'，5'-e）吡嗪的简易合成和硝化

Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systems

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