Are branched chain fatty acids the natural substrates for P450(BM3)?

Cryle MJ; Espinoza RD; Smith SJ; Matovic NJ; De Voss JJ

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Are branched chain fatty acids the natural substrates for P450(BM3)?

机译：支链脂肪酸是P450（BM3）的天然底物吗？

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Branched chain fatty acids are substrates for cytochrome P450(BM3) (CYP102) from Bacillus megaterium; oxidation of C-15 and C-17 iso and anteiso fatty acids by P450(BM3) leads to the formation of hydroxylated products that possess high levels of regiochemical and stereochemical purity.

机译：支链脂肪酸是巨大芽孢杆菌细胞色素P450（BM3）（CYP102）的底物； P450（BM3）氧化C-15和C-17异脂肪酸和前异脂肪酸会导致形成羟基化的产物，这些产物具有较高的区域化学和立体化学纯度。

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来源
《Chemical Communications》 |2006年第22期|p. 2353-2355|共3页
作者
Cryle MJ; Espinoza RD; Smith SJ; Matovic NJ; De Voss JJ;
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作者单位

Univ Queensland, Dept Chem, Brisbane, Qld 4072, Australia;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
BACILLUS-MEGATERIUM; CYTOCHROMES P450; SUBTILIS; PURIFICATION; CYCLOPROPYL; EXPRESSION; REDUCTION; OXIDATION; ALCOHOLS; KETONES;

机译：芽孢杆菌;细胞色素P450;亚取代;纯化;环丙基;表达;还原;氧化;醇;酮;

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机译：短支链C6羧酸导致单核细胞增生性李斯特菌（Listeria monocytogenes）支链脂肪酸缺陷型突变体的生长增加，新的“非天然”脂肪酸和膜流动性增加
2. Enzyme-substrate complementarity governs access to a cationic reaction manifold in the P450_(BM3)-catalysed oxidation of cyclopropyl fatty acids [J] . Cryle M.J., Hayes P.Y., De Voss J.J. Chemistry: A European journal . 2012,第50期

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4. Branched-Chain Fatty Acids in the Neonatal Gut and Estimated Dietary Intake in Infancy and Adulthood [C] . Rinat R. Ran-Ressler, Raymond P. Glahn, SangEun Bae, Nestlé Nutrition Workshop . 2013

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机译：短支链C6羧酸导致单核细胞增生性李斯特菌中的生长增加新型非天然脂肪酸和膜流动性增加支链脂肪酸缺陷型突变体
7. The branched-chain fatty acids of butterfat. 1. The isolation from butterfat of branched-chain fatty acids with special reference to the C17 acids [O] . Hansen, R. P., Shorland, F. B. 1951

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Are branched chain fatty acids the natural substrates for P450(BM3)?

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